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Grupo La Casa Mutante

Público·26 miembros

Dmg Properties


DMG Property Group is the leading real estate company in North Cyprus. We build, develop and market hundreds of properties for sale in the best locations in North Cyprus. DMG Group has over 30 years experience in tourism and real estate industries and has an excellent reputation as reliable and trustworthy group of companies.

Dimethylglyoxime (DMG) usually forms thermodynamically stable chelating complexes with selective divalent transition-metal ions. Electronic and spectral properties of metal-DMG complexes are highly dependent on the nature of metal ions. Using range-separated hybrid functional augmented with dispersion corrections within density functional theory (DFT) and time-dependent DFT, we present a detailed and comprehensive study on structural, electronic, and spectral (both IR and UV-vis) properties of M(DMG)2 [M = Ni2+, Cu2+] complexes. Ni(DMG)2 results are thoroughly compared with Cu(DMG)2 and also against available experimental data. Stronger H-bonding leads to greater stability of Ni(DMG)2 with respect to isolated ions (M2+ and DMG-) compared to Cu(DMG)2. In contrast, a relatively larger reaction enthalpy for Cu(DMG)2 formation from chemically relevant species is found than that of Ni(DMG)2 because of the greater binding enthalpy of [Ni(H2O)6]2+ than that of [Cu(H2O)6]2+. In dimers, Ni(DMG)2 is found to be 6 kcal mol-1 more stable than Cu(DMG)2 due to a greater extent of dispersive interactions. Interestingly, a modest ferromagnetic coupling (588 cm-1) is predicted between two spin-1/2 Cu2+ ions present in the Cu(DMG)2 dimer. Additionally, the potential energy curves calculated along the O-H bond coordinate for both complexes suggest asymmetry and symmetry in the H-bonding interactions between the H-bond donor and acceptor O centers in the solid-state and in solution, respectively, well corroborating with early experimental findings. Interestingly, a lower proton transfer barrier is obtained for the Ni(DMG)2 compared to its Cu-analogue due to stronger H-bonding in the former complex. In fact, relatively weaker H-bonding in Cu(DMG)2 results in blue-shifted O-H stretching modes compared to that in Ni(DMG)2. On the other hand, qualitatively similar optical absorption spectra are obtained for both complexes with red-shifted peaks found for the Cu(DMG)2. Finally, computational models for axial mono- and diligand (aqua and ammonia) coordinated M(DMG)2 complexes are predicted to be energetically feasible and stable with relatively greater binding stability obtained for the ammonia-coordination.

Among the properties in the DMG/Noah Properties portfolio are Roselle Station Apartments in Roselle, IL; Bloomingdale Trails Apartments in Bloomingdale, il; and Galewood Flats in Northwest Chicago (pictured). Currently, DMG, led by managing broker Roger Daniel, has a management portfolio of more than 1,500 units.

Under shear stress (e. g. when inserting the tray into the mouth) the viscosity properties change and Honigum-Light overcomes the alleged opposites: the initially stable material flows below the preparation line and thus provides a perfect detail reproduction

Its combination of zirconia filler and DMG patented nanotechnology significantly improves strength, flowability and physical properties, making it ultra-strong and reliable; it's the ultimate in resin technology for excellent fitting, long-lasting restorations and happy patients alike.

The material's outstanding flow properties guarantee optimum adaptation to the shape of cavity walls and posts. The thin film thickness of just 20 μm is ideal when used for post cementation. (According to ISO 4049 the limit for precision cement is 25 μm).

cfgDMG = wlanDMGConfig(Name,Value) sets properties using one or more name-value pairs. Enclose each property name in quotation marks. For example, wlanDMGConfig('MCS','13','TrainingLength',4) specifies a DMG format with these properties:

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